For a perfect gas the specific heat at constant pressure Cp and that at constant volume Cv are related as:-

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  1. Cp = Cv
  2. Cp = Cv + R
  3. Cp = Cv - R
  4. Cp = Cv + log R

Answer (Detailed Solution Below)

Option 2 : Cp = Cv + R
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Concept:

  • Perfect gas or ideal gas is the hypothatical condition which obeys the ideal gas law or the real nature of gas that is why its ideal condition.
  • Specific heat is the quantity of heat required to raise the temperature of unit mass of the gas by 1 degree.
  • Specific heat at constant pressure CP is the quanity of heat required to raise 1 degree at constant pressure, and Specific heat CV is the quantity of heat required to raise 1 degree at constant volume.

the specific heat is at constant pressure (Cp) is greater then the specific heat at constant volume (CV) And the gas constant can be expressed as C- CV = R, this relation is termed as Mayer’s Formula.

Where,

R = Gas constant

n = molar mass of the substance

Cp= molar specific heat at constant pressure

C= molar specific heat at constant Volume

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