Identify the following reaction

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AIIMS BSc NURSING 2023 Memory-Based Paper
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  1. Wurtz reaction
  2. Stephen reaction
  3. Cannizzaro reaction
  4. Sandmeyer's reaction

Answer (Detailed Solution Below)

Option 3 : Cannizzaro reaction
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CONCEPT:

Cannizzaro Reaction

  • The Cannizzaro reaction is a chemical reaction that involves the base-induced disproportionation of an aldehyde lacking an alpha hydrogen atom.
  • In this reaction, one molecule of the aldehyde is reduced to the corresponding alcohol, while another molecule is oxidized to the corresponding carboxylic acid.

EXPLANATION:

  • In the given reaction:

    2 R-CHO + NaOH → R-CH2OH + R-COONa

cannizzaro-reaction-c42abb32

    • In the presence of a strong base like NaOH, two molecules of the aldehyde react.
    • One aldehyde molecule is reduced to the corresponding alcohol (R-CH2OH).
    • The other aldehyde molecule is oxidized to the corresponding carboxylate ion (R-COONa).

Therefore, the given reaction is an example of the Cannizzaro reaction.

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