The given molecular orbital configuration of diatomic molecule

(2sσg)2 (2sσu)2 (2pσg)2 (2pπu)4 stands for 

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BPSC AE Paper 3 (General Studies) 10 Nov 2022 Official Paper
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  1. N2
  2. CO
  3. OH
  4. O2

Answer (Detailed Solution Below)

Option 4 : O2
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CONCEPT:

Molecular Orbital Theory for Diatomic Molecules

  • Molecular orbital (MO) theory describes the distribution of electrons in molecules in terms of molecular orbitals that can extend over the entire molecule.
  • In diatomic molecules, the combination of atomic orbitals from two atoms results in the formation of bonding and antibonding molecular orbitals.
  • The given molecular orbital configuration represents the arrangement of electrons in these molecular orbitals.
  • The specific configuration  \((2s\sigma_g)^2 (2s\sigma_u)^2 (2p\sigma_g)^2 (2p\pi_u)^4\) needs to be matched with a known diatomic molecule.

Explanation:-

  • Total electrons in the configuration:
    • (2s\sigma_g)2 : 2 electrons
    • (2s\sigma_u)2 : 2 electrons
    • (2p\sigma_g)2 : 2 electrons
    • (2p\pi_u)4 : 4 electrons
  • Total number of electrons: 2 + 2 + 2 + 4 = 10
  • The molecule with 10 valence electrons that matches this configuration is O2 .

The given molecular orbital configuration of the diatomic molecule

\((2s\sigma_g)^2 (2s\sigma_u)^2 (2p\sigma_g)^2 (2p\pi_u)^4 \)stands for O2

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