Question
Download Solution PDFRMgX + CO2 \(\rm \xrightarrow[ether]{dry}\) Y \(\rm \xrightarrow{ \ \ H_3O^+ \ \ }\) RCOOH
What is Y in the above reaction?
Answer (Detailed Solution Below)
Detailed Solution
Download Solution PDFConcept:
Reaction of Grignard reagent with CO2 -
- It is an important method of preparation of carboxylic acid.
- Grignard reagent behaves as a nucleophile which attacks the substrate CO2 in presence of dry ether and forms a nucleophilic addition product.
- This nucleophilic addition product is a salt of carboxylic acid which on acidification yields carboxylic acid.
Explanation:
In the given reaction, R-MgX is the Grignard reagent and CO2 (dry ice) is the substrate.
The reaction is complete in two steps-
- Attack of Grignard reagent on CO2 - the nucleophile Grignard reagent attack the CO2 in presence of dry ether and as a carboxylic acid salt is formed as product name as 'Y' in the above reaction.
- Acidification of the carboxylic salt - It gives carboxylic acid as a final product.
It can be represented as -
Rδ--δ+MgX + O=C=O \(\xrightarrow{dry \hspace{0.1cm}ether}\) RCOO- Mg+X \(\xrightarrow{H_3O^+}\) RCOOH
So, RCOO- Mg+X is obtained as an intermediate product (Y) in the given reaction.
Hence, the correct answer is option 2.
Last updated on Jun 16, 2025
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