The coefficient of volume expansion of glycerine is 49 × 10-5 K-1. Find the fractional change in its density for a 20° C rise in temperature?

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  1. 2.45 × 10-2
  2. 98 × 10-2
  3. 0.49 × 10-2
  4. 0.98 × 10-2

Answer (Detailed Solution Below)

Option 4 : 0.98 × 10-2
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CONCEPT

According to the formula for the increase in volume due to temperature change 

\(V_f = V_0(1+γΔ T)\)

Where γ = coefficient of volume expansion 

ΔT is the change in volume

V0 and Vf are the initial and final volumes respectively

CALCULATION

Given: γ = 49 × 10-5K-1, ΔT = 20oC

Now

Vf = V0(1+ 49 × 10-5× 20)

\(\frac{V_f}{V_0} = 1.0098\)

For the change in density 

\(\rho = \frac{m}{V}\)

the fractional change in density 

\(\frac{\rho_f - \rho_0}{\rho_0} = \frac{\frac{m}{V_f} - \frac{m}{V_0}}{\frac{m}{V_0}}\)

\(⇒ \frac{\Delta \rho}{\rho_0}= \frac{V_0}{V_f} -1\)

\(⇒ \frac{\Delta \rho}{\rho_0} = \frac{1}{1.0098} -1\)

\(⇒ \frac{\Delta\rho}{\rho_0} = -9.8 × 10^{-3}\)

\\(⇒ \frac{\Delta\rho}{\rho_0} = -0.98× 10^{-2}\)

The negative sign represents there is a decrease in the density of the glycerine.

Hence the correct answer is 0.98 × 10-2

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